Preheat the oven to 350°F and line 24 cupcake wells with liners. Set aside.
In a bowl, whisk together the cake flour, cocoa powder, baking soda, and salt until evenly combined. Set aside.
In a large mixing bowl, combine the vanilla, buttermilk, eggs, and oil. Stir until combined.
Add the sugar and mix until combined.
Stir in the vinegar and food dye until evenly incorporated.
Add the dry ingredients to the wet ingredients, stirring until just combined.
Stir in the hot water. The batter will be thin.
Pour the batter into the 24 lined cupcake wells and bake for about 20 minutes, or until a toothpick inserted in the center comes out clean.