In a bowl, whisk together the sugar, flour, cocoa powder, baking soda, baking powder, and salt until evenly combined.
Add the egg, vanilla, buttermilk, and oil. Mix until combined.
Stir in the hot coffee quickly to ensure even distribution. The batter will be thin.
Pour the batter over the baked crust, filling each cup about two-thirds full.
Bake at 350°F for about 20 minutes, or until a toothpick inserted into the center comes out clean.