Preheat the oven to 350°F.
Combine sugar, flour, cocoa powder, baking soda, baking powder, and salt in a bowl. Stir together with a whisk until evenly mixed.
Add vanilla, eggs, buttermilk, and oil. Stir until combined.
Add hot coffee and stir quickly to mix evenly. The batter will be very thin.
Pour the batter into a greased and floured 9x13" pan.
Bake for about 20 minutes or until a toothpick comes out clean.
Set aside to cool.