Preheat your oven to 350 degrees Fahrenheit. Line a cupcake pan with 12 liners.
In a medium bowl, whisk together the cake flour, baking powder, baking soda, and salt. Set aside.
In a large bowl, cream together the butter and granulated sugar until fluffy.
Add the egg whites and vanilla, mixing until pale and smooth.
Alternate adding the dry ingredients and buttermilk to the butter mixture, mixing until smooth.
Fold in the rainbow jimmies.
Divide the batter evenly among the liners and bake for 16 to 18 minutes.
Let the cupcakes cool before frosting.