Preheat the oven to 350°F. Line a 12-cup muffin tin with paper or foil liners.
In a stand mixer, combine melted butter, oil, vanilla, hot coffee, and sugar. Mix until well combined.
In a separate bowl, sift together flour, cocoa powder, baking soda, and salt. Slowly add the dry ingredients to the mixer on low speed.
With the mixer on low, add the egg and buttermilk. Mix until just combined.
Fill muffin tins with batter (about 3/4 full) and bake for 25-30 minutes. Allow cupcakes to cool completely.